Canon R6 V has a
32.5MP Full frame (36 x 24 mm ) sized CMOS sensor and features Digic X processor. On the other hand, Sony A9 III has a
24.6MP Full frame (35.6 x 23.8 mm ) sized Global Shutter sensor and features BIONZ XR processor.
Canon R6 V's sensor provides 7.9MP more than Sony A9 III's sensor, which gives a significant advantage in real life. You can print your images larger or crop more freely.
On the other hand, please keep in mind that Max sensor resolution is not the only determinant of resolving power. Factors such as the optical elements, low pass filter, pixel size and sensor technology also affects the final resolution of the captured image.
One other difference between these two cameras that is worth mentioning is that Sony A9 III's sensor doesn't have an anti-alias (Low-Pass) filter. Removing anti-alias filter increases the sharpness and level of detail but at the same time, it increases the chance of moiré occurring in certain scenes.
Below you can see the R6 V and A9 Mark III sensor size comparison.
Sensor Size and Resolution Comparison image of Canon R6 V and Sony A9 III Cameras
Canon R6 V and Sony A9 III have almost the same sensor size, so neither of them has any significant advantage over the other in terms of providing control over depth of field when used with the same focal length and aperture.
Sensor size sets the circle of confusion, so it drives how much depth of field each
of these bodies gives you at a given aperture. You can calculate it exactly for the
Canon R6 V
or the
Sony A9 III ,
including hyperfocal distance.