Sony A6100 has a 24.0MP APS-C (23.5 x 15.6 mm ) sized CMOS sensor and features Bionz X processor. On the other hand, Canon R5 has a 45.0MP Full frame (36 x 24 mm ) sized CMOS sensor and features Digic X processor.
Canon R5's sensor provides 21MP more than Sony A6100's sensor, which gives a significant advantage in real life. You can print your images larger or crop more freely.
On the other hand, please keep in mind that Max sensor resolution is not the only determinant of resolving power. Factors such as the optical elements, low pass filter, pixel size and sensor technology also affects the final resolution of the captured image.
Below you can see the A6100 and R5 sensor size comparison.
As seen above, Canon R5 has a 2.4x Larger sensor area than Sony A6100. Larger sensors give photographer more control on the depth of field and blurry background compared to smaller sensor when shot in same focal length and aperture.