Samsung Galaxy NX has a 20.0MP APS-C (23.5 x 15.7 mm ) sized CMOS sensor and features DRIMe IV processor. On the other hand, Nikon Z7 has a 46.0MP Full frame (35.9 x 23.9 mm ) sized BSI-CMOS sensor and features Expeed 6 processor. Nikon Z7's sensor provides 26MP more than Samsung Galaxy NX's sensor, which gives a significant advantage in real life. You can print your images larger or crop more freely.
On the other hand, please keep in mind that Max sensor resolution is not the only determinant of resolving power. Factors such as the optical elements, low pass filter, pixel size and sensor technology also affects the final resolution of the captured image.
Below you can see the Galaxy NX and Z7 sensor size comparison.
As seen above, Nikon Z7 has a 2.3x Larger sensor area than Samsung Galaxy NX. Larger sensors give photographer more control on the depth of field and blurry background compared to smaller sensor when shot in same focal length and aperture.