Olympus E-330 has a
7.0MP Four Thirds (17.3 x 13 mm ) sized CMOS sensor . On the other hand, Olympus PEN-F has a
20.0MP Four Thirds (17.3 x 13 mm ) sized CMOS sensor and features TruePic VII processor.
Olympus PEN-F's sensor provides 13MP more than Olympus E-330's sensor, which gives a significant advantage in real life. You can print your images larger or crop more freely.
On the other hand, please keep in mind that Max sensor resolution is not the only determinant of resolving power. Factors such as the optical elements, low pass filter, pixel size and sensor technology also affects the final resolution of the captured image.
Below you can see the E-330 and PEN-F sensor size comparison.
Olympus E-330 and Olympus PEN-F have the same sensor sizes so they will provide same level of control over the depth of field when used with same focal length and aperture.