FujiFilm S2500HD has a 12.0MP 1/2.3-inch (6.17 x 4.55 mm ) sized CCD sensor . On the other hand, Samsung NX210 has a 20.0MP APS-C (23.5 x 15.7 mm ) sized CMOS sensor .
Samsung NX210's sensor provides 8MP more than FujiFilm S2500HD's sensor, which gives a significant advantage in real life. You can print your images larger or crop more freely.
On the other hand, please keep in mind that Max sensor resolution is not the only determinant of resolving power. Factors such as the optical elements, low pass filter, pixel size and sensor technology also affects the final resolution of the captured image.
Below you can see the S2500HD and NX210 sensor size comparison.
As seen above, Samsung NX210 has a 13.1x Larger sensor area than FujiFilm S2500HD. Larger sensors give photographer more control on the depth of field and blurry background compared to smaller sensor when shot in same focal length and aperture.