Canon G1 X III has a 24.0MP APS-C (22.3 x 14.9 mm ) sized CMOS sensor and features DIGIC 7 processor. On the other hand, Sigma SD14 has a 5.0MP APS-C (20.7 x 13.8 mm ) sized CMOS (Foveon X3) sensor .
Canon G1 X III's sensor provides 19MP more than Sigma SD14's sensor, which gives a significant advantage in real life. You can print your images larger or crop more freely.
On the other hand, please keep in mind that Max sensor resolution is not the only determinant of resolving power. Factors such as the optical elements, low pass filter, pixel size and sensor technology also affects the final resolution of the captured image.
Below you can see the G1 X III and SD14 sensor size comparison.
As seen above, Canon G1 X III has a 1.2x Larger sensor area than Sigma SD14. Larger sensors give photographer more control on the depth of field and blurry background compared to smaller sensor when shot in same focal length and aperture.