Canon SL2 has a 24.0MP APS-C (22.3 x 14.9 mm ) sized CMOS sensor and features DIGIC 7 processor. On the other hand, Pentax K-500 has a 16.0MP APS-C (23.7 x 15.7 mm ) sized CMOS sensor and features PRIME M processor. Canon SL2's sensor provides 8MP more than Pentax K-500's sensor, which gives a significant advantage in real life. You can print your images larger or crop more freely.
On the other hand, please keep in mind that Max sensor resolution is not the only determinant of resolving power. Factors such as the optical elements, low pass filter, pixel size and sensor technology also affects the final resolution of the captured image.
Below you can see the SL2 and K-500 sensor size comparison.
As seen above, Pentax K-500 has a 1.1x Larger sensor area than Canon SL2. Larger sensors give photographer more control on the depth of field and blurry background compared to smaller sensor when shot in same focal length and aperture.